The gravitational potential of an object around the sun, relative to some point far far away (from the sun), should be smaller zero and proportional to $V_{escape}^2$. Hence the speed one needs should be $V_{mission}=\sqrt{V_{escape1}^2-V_{escape2}^2}$ with $V_{escape1}$ The escape velocity at the starting point relative to the sun.
The list of escape velocities states the Escape Velocity at the Earth Orbit relative to the Suns gravity as 42,1 km/s, at Jupiter (relative to the Sun) 18,5 km/s. So I would expect the lowest possible Delta V for a mission to fly to Jupiter would be the difference, or 37.6 km/s without taking into account leaving LEO or braking inside Jupiters gravity well.
Now, the NASA trajectory browser typically gives Mission delta Vs around 5km/s. So obviously my quick and dirty calculation above is wrong.
What is a working, quick way to calculate the lowest possible mission delta v to reach a point higher in a gravity well, using the data in the list of Escape velocities?