2
$\begingroup$

this question made me think what type of technique is used to get concentration of gases on planets?

One can get the composition using spectrometry but is there anyway to tell concentration of each gas by some chemical analysis or anything else?

Or maybe by doing a frequency sweep on a sample of gas and then seeing absorption graph then comparing with composition of atmosphere and combining with known absorption of gases determining the concentration of various gases?

$\endgroup$
  • $\begingroup$ There are several methods, some used from a large distance and others from a probe within the atmosphere. $\endgroup$ – Uwe Apr 27 '18 at 8:55
3
$\begingroup$

The concentration of an atmospheric constituent is the number of molecules of that chemical species per volume, and that varies with pressure and temperature. In planetary atmospheric science we usually refer instead to abundance, often specifying it by the species's mixing ratio: given a sample of the atmosphere, the fraction of the total number of molecules in the sample that are molecules of that species. In the absence of complications like condensation or chemical reactions, the mixing ratio doesn't vary with temperature or pressure. With regard to measuring the abundance of constituents in an atmosphere via remote sensing, so far spectroscopy is indeed the best way. The frequencies of absorption/emission lines observed (any gas's spectral lines can be seen in either absorption or emission, depending on the circumstances) identify which chemical species are there. But in spectroscopy not only do you measure line frequencies, you also measure the intensity of the lines, i.e. how much the constituent is absorbing or emitting whatever kind of electromagnetic radiation you're observing (light, radio, etc.), and the shape of the lines when plotted as intensity vs. frequency. The intensity tells you how much of that constituent is there. If you can measure the intensities of multiple lines from the same constituent, you can even estimate its temperature! The shape of those lines also changes with the pressure of the gas: as the pressure increases, the line width, the range of frequencies the line spans, also increases. This is called pressure broadening. If the lines are strong enough (you have a high enough signal-to-noise ratio, SNR), you can use the line widths to measure the atmospheric pressure at the altitudes where the absorption or emission is occurring. Usually the lines you observe are combinations over a range of altitudes in an atmosphere, and that means a range of pressures and temperatures. This makes for very complex line shapes. If the SNR is high enough, you can sort out which parts of the line's shape are due to molecules at which pressures, so you can roughly infer the temperature-pressure profile, the temperature as a function of atmospheric pressure.

$\endgroup$
  • $\begingroup$ Amazing how planetary scientist derive so much from so less ! $\endgroup$ – Prakhar Apr 28 '18 at 16:51

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy

Not the answer you're looking for? Browse other questions tagged or ask your own question.