@MarkAdler's comment led me to ask Why would a slow spiral from a C3 of zero take about 2.4 times as much ΔV as an impulsive maneuver? which resulted in this tidy and efficient @MarkAdler answer which points to another thoughtful answer about slowly spiraling out from a circular orbit to escape in the limit of very weak prograde propulsion, which (at first counterintuitively) slows you down while raising your orbit.
Below that answer is yet another easter-egg-like comment gem.
Always aligned with the velocity vector. That is the most efficient use of the thrust in order to increase the specific energy. The final γ is 31°†.
Question: In this context, what is the angle γ? How is it defined?
† The phenomenon is correct but 31° was a typo and should be about 39.2° instead.