@Tristan's answer says:
The satellites are classified, so details are speculative, but it is believed that the Magnum/Orion and Mentor SIGINT satellites have parabolic antennae around 100 m in diameter.
which for an antenna hound like me is really, really intriguing. Is there any more information about that?
The answer to What's the largest area dish antenna sent beyond the Earth-Moon system? is Galileo's 4.6 meter dish.
Besides that as it may be very hard to confirm at all, what is or are the largest antennas deployed in space? They would not have to be dishes, but nonetheless I've listed two below. And masts don't count!
Some fairly large ones include Queqiao:
Source from Why is Queqiao's dish antenna so big? (Chang'e-4 relay satellite) Largest ever on/near the Moon?
And Spektr-R:
Source: @BowlOfRed's answer