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The Ars Technica article SpaceX scrubs first attempt to launch 60 Internet satellites [Updated] (found here) discusses the use of Krypton rather than Xenon in the Starlink Hall effect ion thrusters:

The satellites are designed to control costs. For example, each will maneuver with Hall-effect thrusters—ion thrusters in which propellant is accelerated by an electric field. The conventional fuel for such a thruster is xenon, which offers high performance. The Starlink satellites, however, will use a different noble gas: krypton. It has a lower density, so the satellite fuel tanks need to be larger, and it offers less performance than xenon. But krypton can be bought at just one-tenth the cost of xenon, which matters if a company wants to fuel thousands of satellites. (emphasis added)

"It costs a heck of a lot less than xenon," Musk said of krypton. (He also joked, in response to a question from Ars about this fuel, that the satellites would be immune to invasion from Superman's native world.)

In this answer I argue that using a lighter ion gives a higher mass-specific impulse or Isp than a heavier heavier one assuming both are +1 and voltage is constant.

So I'm wondering exactly what performance specification is lower for Krypton than Xenon as mentioned in the quote.

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    $\begingroup$ I'm guessing (that's why this is a comment) that it's something to do with impulse per Joule of electrical power. Xenon has a lower ionization energy, so less energy is wasted by the fact that the exhaust is ions and electrons, rather than whole atoms. $\endgroup$ – Steve Linton May 16 at 20:07
  • $\begingroup$ @SteveLinton I think you are on to something. More power to run the plasma may also require heavier electronics or magnets, showing up as a lower thrust-to-weight ratio. $\endgroup$ – uhoh May 16 at 20:51
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Hall effect thrusters do not use strong magnetic fields and radio frequency power to heat electrons to high energy for ionization of the gas. Instead they rely on a DC current of electrons accelerated to a few hundred volts flowing through the gas volume for ionization. Since Krypton has a higher ionization potential than Xenon (roughly 14.0 versus 12.1 eV), either the ionization efficiency will be lower or it will require a higher cathode power.

In addition, the higher energy electrons will need a higher magnetic field to contain them, which increases coil current and mass of the magnetic circuit. The higher energy electrons will also erode the thruster more quickly, reducing usable life.

The higher velocity of Krypton (at a given acceleration potential) means higher Isp, but lower overall thrust and/or energy efficiency. With electric propulsion, you trade thrust to power ratio and Isp. It's all tunable based on mission impulse and timelines. Hall thrusters have lower Isp, but more thrust, while ion thrusters have much higher Isp, but far lower thrust. So for long missions with high impulse (like Dawn) use ion systems, while orbital stuff tends to trade better with Hall systems.

Another change is related to the torque produced by a Hall current thruster. As the ions are accelerated through the plasma, the radial magnetic field that traps the plasma electrons will give a small kick to the departing ions. This resulting in a torque along the thrust axis. It's not large because the charge to mass ratio of the xenon ions is very low, but it's big enough that it must be compensated for. Krypton has a higher charge to mass ratio, so the angular deflection will be larger. This will increase the torque relative to the thrust, and require more compensation. Depending on how many thrusters they're using, it could complicate orbital maintenance.


Hall effect thruster Hall effect thruster Source and Source

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  • $\begingroup$ Hall effect thrusters are a type of Ion engine. Agreed that higher ionization potentials but lower molecular weight (hence ISP) are the tradeoffs. @uhoh are both basic well understood bits of chemistry and should not need references. $\endgroup$ – ANone May 17 at 11:41
  • $\begingroup$ The cathode creates a stream of electrons generated by a high bias voltage and a low work function material to blast the working fluid to ions in the circular channel (which is why it glows). For krypton, you need much more energetic electrons than you would for xenon. This significantly increases the erosion rate, which will shorten the life of the thruster. I recommend "Fundamentals of Electric Propulsion: Ion and Hall Thrusters" by Dan M. Goebel and Ira Katz. It's the textbook I worked from, and you can download it for free from NASA. It does a pretty good job of explaining the trades. $\endgroup$ – RocketDocRyan May 18 at 5:19
  • $\begingroup$ I also apologize for being only somewhat coherent. I'm on mobile, and it's been a really long week. $\endgroup$ – RocketDocRyan May 18 at 5:35
  • $\begingroup$ I've made an edit based on comments. It's the first time I've actually looked at a diagram about Hall effect thrusters! Feel free to modify further or roll back. $\endgroup$ – uhoh May 19 at 11:38
  • $\begingroup$ I was planning to make some edits on Monday when I get some downtime. Yours look great, though. These things have a lot going on, so it's really hard to sum them up succinctly. Everything affects everything else, so it's hard to contain the effects of a single change. $\endgroup$ – RocketDocRyan May 19 at 13:26
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Higher power required for same thrust efficiency

Confirming @ RocketDocRyan's answer higher power is required for the same thrust efficiency for krypton than for xenon.

Higher erosion rate

Erosion rate might be a secondary specification that is worse (faster) for krypton than for xenon.

According to Wikipedia's Starlink (satellite constellation); Satellite hardware:

Starlink satellites use Hall-effect thrusters with krypton gas as the reaction mass[44][64] for orbit raising and attitude control.65 Krypton Hall thrusters tend to exhibit significantly higher erosion of the flow channel compared to a similar electric propulsion system operated with xenon, but at a lower propellant cost.66

65 ESA artes: KHT - Krypton Hall Thrusters - Identification, Evaluation and Testing of Alternative Propellants for Electric Propulsion Systems

66 Teslarati: SpaceX’s Starlink satellite lawyers refute latest “flawed” OneWeb critique


From here:

Traditionally, xenon has always been the propellant of choice for EP applications due to the optimal compromise between performance and ease of handling. Although xenon has several technical advantages, its high price suffers of a remarkable fluctuation, posing serious budget concerns. To reduce propellant cost, a more economical alternative to xenon needs to be identified, while retaining thruster performance levels, without disregarding crucial system level considerations.

The KHT project plan focuses on an experimental campaign to test, with pure krypton and with different Kr-Xe blends, a 5 kW Hall-effect thruster, the Sitael-HT5k, designed to operate with xenon. Main objectives of the test campaign are: (i) characterisation of thruster performances and comparison with xenon as a benchmark; (ii) assessment of the erosion evolution of the channel walls; (iii) validation of a reduced order performance and erosion model; (iv) extrapolation of the effect of alternative propellants on lifetime and EOL performance; (v) assessment of system level implications related to the use of alternative propellants.

The HT-5k thruster unit showed a stable operation with the selected alternative propellants over a wide range of discharge voltages (250-600V) and powers (2-7 kW). The thruster was capable to reach high thrust efficiencies also with pure krypton. In general, with the transition from pure xenon to pure krypton the maximum of the thrust efficiency showed a shift towards higher power levels (4000-4500W for pure Xe; ~6500W for pure Kr). The thruster showed a stable discharge current trend with no issues of flame-out or overheating. Plume measurements indicated that beam divergence depends on the amount of krypton in the mixture: the higher the percentage of krypton, the larger the beam divergence. As expected, pure Kr and Kr blends showed to increase significantly the initial erosion rate of the ceramic channel.

xenon vs krypton Hall effect thruster erosion

xenon vs krypton Hall effect thruster erosion

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