That depends entirely on what rocket and airplane you are comparing, of course.
However, with regard specifically to the large rockets used for spaceflight against commercial aviation, yes. Orbital speed is approximately 8 km/s for Earth at a low orbit. A typical commercial jetliner flies at speeds of around 0.25 km/s. That's all it takes to know which is "faster".
How fast things "appear" to be moving, however, is a rather different matter, and a huge function of observer perspective. "Apparent" motion is really the crossing of your visual field at a given rate, and this can be seen by noting that it is not measured in units of physical speed (m/s, km/s, km/h, MPH, etc.) but in units of angle per time, e.g. rad/s, mrad/s, deg/s. This depends on all of:
- the actual speed of the object,
- the distance to the object from your observing point, and
- the angle its trajectory makes with the line from your eyes to it.
. Note that as the distance is changing, so too will the apparent speed through the course of the flight: think about a car going by you - its apparent speed is fastest at closest approach when it passes your perpendicular to the roadway, and then slows as it recedes.
The relevant expression can be derived from trigonometry: it is
$$\mbox{Visual speed} = \frac{\mbox{Actual speed}}{\mbox{Observer distance}} \cdot \sin(\theta)$$
where $\theta$ is the angle in the third bulletpoint. Note that the visual speed is, as just mentioned, maximized when moving perpendicular to your line of sight, i.e. $\theta = 90^{\circ}$ or $\frac{\tau}{4}\ \mathrm{rad}$.
So an airplane at a distance of 10 km above your head, looking straight up and traveling at 0.25 km/s horizontally, has an angular speed of 0.025 rad/s or 25 mrad/s. A rocket which is maybe about 50 km up and going 2 km/s, say, would have an angular speed of 40 mrad/s if it were traveling similarly transversally, but if the angle to your vision is, say, 250 mrad (approx. $14^{\circ}$) as may be expected from an upward trajectory, then it will only have an apparent speed of 10 mrad/s, less than half as much. This is why a rocket appears slower, as you observe, during the launch phase.