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Most modern rocket analysis methods can base calculations on either Gibbs free energy or the Helmholtz free energy when computing what the exhaust products (and hence, the exhaust velocity) will be (sources: Sutton & Biblarz, 2010; Gordon & McBride, 1994; Ponomarenko, 2009; one counterexample (but much older): Reynolds, 1986). One requires the assumption of constant given pressure; the other, a constant given volume. When a (well running!) rocket engine is at full thrust, both are true in the combustion chamber, no?

So why is one picked over the other? Wouldn't it be easier to say "I'll have this size combustion chamber" and then figure out the pressure (and thus: throat nozzle) from there? Yet it (from my reading) that assuming a chamber pressure to start is the norm.

Which would be easier to start with--a given pressure or a given volume--if you are trying to develop an engine that will have a certain amount of thrust?

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    $\begingroup$ How do you design the turbo pumps for the propellants and the walls of the combustion chamber when knowing the chamber volume? You need to know chamber pressure for that design. $\endgroup$
    – Uwe
    May 20, 2020 at 19:14
  • $\begingroup$ @Uwe That looks very much like an answer. Fancy turning it into one? $\endgroup$
    – TooTea
    May 20, 2020 at 19:34

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When designing a rocket engine you need to design the turbo pumps for the propellants and the combustion chamber.

To design a turbopump you need to know its output pressure and the volume flow rate. To determine the output pressure you need to know the chamber pressure.

To design the walls of the combustion chamber you need to know the chamber pressure to compute the neccessary wall thickness.

So you cant design a rocket engine when knowing only the chamber volume, you need to know the chamber pressure.

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