Was there any Space Shuttle mission whose primary target were e deploying satellites (space stations do not count).
These early missions launched comsats for paying customers.
STS-5, 7, 8, 41-B, 41-D, 51-A, 51-D, 51-G, 51-I, 61-B, 61-C, 49
These missions launched geosynchronous comsats for NASA or other government agencies
STS-6, 26, 29, 32, 43, 54, 51, 70
These missions launched Earth-orbiting scientific or unclassified defense satellites for NASA or other government agencies
STS-41C, 41-G, 61-A, 31, 37, 48, 44, 46, 52, 53, 60, 63, 93
The payloads on several DOD dedicated missions remain classified.
This list does not include
satellites deployed from the shuttle and retrieved during the same mission.
tiny satellites for universities, etc., as Getaway Specials or other add-on payloads.
Reference: Space Shuttle Missions Summary