The general answer is $$fuel\;fraction= 1-\frac{\sqrt{r} -1}{r-1} $$
where the fuel fraction is the fraction of the mass of fuel used in the first burn over the total fuel mass, and $r$ is the fuel mass ratio of the whole craft,( $r = \frac{m_0}{m_1} $ where $m_0$ is the total initial mass of the craft and $m_1$ is the dry mass of the craft)
My derivation:
$m_0$ = The initial mass of the craft. Payload + full load of fuel.
$m_1$ = The final mass of the craft. Just the payload, all fuel is expended.
$m_{1/2}$ = The mass of the craft at the halfway point
In order to accelerate to a given velocity and decelerate back down to zero, you must expend half your delta-V in each burn.
This can be expressed in terms of the rocket equation as follows:
$$ v_e ln \left( \frac{m_0}{m_1} \right) = 2v_e ln \left( \frac{m_0}{m_{1/2}} \right) $$
Or in plain english, the full burn has twice the delta V as the halfway burn.
By doing some cancellation and exponentiating both sides, we end up with:
$$ \left( \frac{m_0}{m_1} \right) = \left( \frac{m_0}{m_{1/2}} \right)^2 $$
This is a useful rule of thumb to remember in general. If you want to double the delta-V of a craft, you need to square the mass ratio. If your rocket is 1:10 payload : fuel and you want to double the delta-V, you need to make the ratio 1:100.
The quantity we are after to solve the problem is not $m_{1/2}$, the total mass after the first burn, it is the fuel fraction $ \frac{m_{1/2}-m_1}{m_0-m_1} $, which is the mass of the fuel left after the first burn divided by the total mass of fuel on the craft.
From rearranging the previous equation, we find that $m_{1/2} = \sqrt{m_0m_1} $ and so we plug that into the fuel fraction to get:
$$ fuel \:fraction =\frac{\sqrt{m_0m_1}-m_1}{m_0-m_1}$$
and then we let $ r = \frac{m_0}{m_1} $ and do some algebra that I am too lazy to reproduce in mathjax here to end up with:
$$ remaining \;fuel\;fraction = \frac{\sqrt{r} -1}{r-1} $$
which of course means that
$$ spent \;fuel\;fraction = 1-\frac{\sqrt{r} -1}{r-1} $$
Let's do some sanity checks. If your craft is the size of the Titanic and its propulsion system consists of two firecrackers. Each firecracker is a 'burn' in one direction. Since the overall mass hardly changes between burns, the expended fuel fraction is approximately 0.5.
If your craft is mostly fuel, you will have a high $r$ value. Since most of the delta-V comes from the last bits of fuel in the tank, you have to burn a huge proportion of the fuel to get to halfway. As $r$ approaches infinity, the fuel fraction for the first burn approaches 1.

To answer your original question with the numbers you supplied, r = 101, so therefore the fraction of fuel you need to burn to the halfway point is 90.95%