To qualify further Russell Borogove's comment:
"94% success is over a long history of rocket development. More recently, launching agencies have refined their designs and processes to achieve really high reliabilities. Atlas II through Atlas V have had only one partial failure in 120 launches since 1991, for example."
Let's take the one partial failure in 120 data and check whether this is statistically significantly lower than the $94\%$ success rate long term. One could apply the right same principles to the different launch vehicle categories on the Comparison of Orbital Launchers Families Wiki page
Assuming the true probability of partial failure were $p=6\%$, as in the figure quoted by Russell's comment, the probability of observing one partial failure or fewer in 120 launches is:
$$\binom{120}{1} p^1\,(1-p)^{119} + \binom{120}{0}\,p^0\,(1-p)^{120}\approx 0.0051$$
i.e. highly statistically significant. So the Atlas data betoken statistically significantly better performance than the $94\%$ long term data.
Now let's estimate a lower bound on the true reliability data. Suppose we reject the null hypothesis at 99% confidence level, then the highest failure rate in keeping with the data at this confidence level is the solution to:
$$\binom{120}{1} p^1\,(1-p)^{119} + \binom{120}{0}\,p^0\,(1-p)^{120}\approx 0.01$$
which comes out to about $p=5.4\%$. So this simple calculation shows that the true long failure rate of the Atlas family since 1991 is at most $5.4\%$ at 99 percent confidence.