I think “primary” is being used in the sense of “of chief importance” since it separates the cabin from vacuum.
Violation from impact is more likely to occur to the “Redundant Pressure Pane” than the “Primary Pressure Pane”.
If the space between the two pressure panes was pressurized, violation of the outer (“Redundant") pane would result in vacuum shock-loading of the inner (“Primary”) pane with 5 tons of pressure. In theory, this shock loading increases the risk of simultaneous catastrophic failure of both pressure panes.
The vacuum between the pressure panes in the ISS differs from the Russian window design. In the Russian design, the space between the panes is pressurized and the outer pane is designated the “Primary Pane”. What are the windows on the Russian segement of the ISS made of?
Early in the NASA assessment of the SM windows there were concerns
that failure of the primary pane might cause failure of the secondary
pane as well due to near instantaneous change in differential pressure
since the volume between the two panes is pressurized. However, tests
conducted by NASA using SM window hardware have demonstrated that the
loss of the primary pane does not result in the loss of secondary
pane.